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The presenters from the movie world were Billy Bob Thornton, Charlize Theron, Cuba Gooding Junior, Danny DeVito, Emily Deschanel, Harrison Ford, Jenna Fischer, John C. Reilly, Josh Duhamel, Kate Hudson, Matthew Broderick, Quentin Tarantino, Rita Moreno, Shirley MacLaine and Jennifer Lopez, who word has it was initially scheduled to perform, until her pregnancy caused her to cancel. The show closed down Hollywood Boulevard, where the stars walked a "green carpet" made of 100-percent recycled materials.
Beyonce, "Over the Rainbow" (The Wizard of Oz)
Mary J. Blige & John Legend - "As Time Goes By" (Casablanca)
Nicole Scherzinger, "Diamonds Are a Girls' Best Friend" (Gentlemen Prefer Blondes)
Jennifer Hudson, "Somewhere" (West Side Story)
Chris Brown, "Jailhouse Rock" (Jailhouse Rock)
Carrie Underwood, "The Sound of Music" (The Sound of Music)
Usher, "Singin' in the Rain" (Singin' in the Rain)
Fergie, "Live and Let Die" (Live and Let Die)
John Williams, "Film Score Medley"
Queen Latifah, "Big Spender" (Sweet Charity)
Elton John, "Can You Feel the Love Tonight" (The Lion King)
Marc Anthony, "Mrs. Robinson" (The Graduate)
Will-I-Am, Busta Rhymes, L-L Cool J & Eve, "Shaft" (Shaft)
Tony Bennett, "White Christmas" (White Christmas) [duetting with Bing Crosby]